Conductivity enhancement within garnet?rich polymer composite electrolytes via the addition of succinonitrile
نویسندگان
چکیده
All-solid-state lithium-ion batteries (ASSLIBs) are promising alternatives to conventional organic electrolyte-based due their higher safety and energy densities. Despite advantages, ASSLIBs suffer from issues like high charge transfer resistances the brittleness of inorganic solid electrolyte chemical instabilities at lithium/electrolyte interface. Within this work, we investigate composite electrolytes (CEs) based on garnet-type Li6.4La3Zr1.4Ta0.6O12 (LLZTO), polyethylene oxide, lithium bis(trifluoromethanesulfonyl)imide, prepared via a solvent-free cryo-milling approach in contrast solvent-mediated synthesis. Compositions ranging polymer-rich garnet-rich systems investigated X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy order determine compatibility process toward membrane fabrication along with possible interactions between components. Electrochemical impedance is used study role ceramic polymer weight fraction ionic conductivity. It shown that addition succinonitrile (SCN) CEs can significantly improve conductivity compared SCN-free CEs.
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s of Papers A-49 Department of Chemistry for Materials
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ژورنال
عنوان ژورنال: International Journal of Applied Ceramic Technology
سال: 2022
ISSN: ['1744-7402', '1546-542X']
DOI: https://doi.org/10.1111/ijac.14184